Chapter 1 Periodic Table, Periodic Properties and Variations of Properties: Concise Chemistry for Class 10
Concise Chemistry for Class 10
Chapter 1 Periodic Table, Periodic Properties and Variations of Properties:
Exercise 1.
Solution 1.
2. Elements of group 1 and elements of group 17 both have valency1. Explain.
Solution 2.
Solution 3.
The horizontal rows are known as periods and vertical columns in the periodic table are known as groups.
4. Periodicity is observed due to the similar.............
Solution 4.
Periodicity is observed due to the similar electronic configuration..
5. How does electronic configuration in atoms change
(i) In a period from left to right?
(ii) In a group top to bottom?
Solution 5.
6. Correct the statements.
(i) Elements in the same period have equal valency.
(ii) Valency depends upon the number of shells in an atom.
(iii) Copper and zinc are representative elements.
(iv) Transition elements are placed at the extreme right of the periodic table.
Solution 6.
(i) Elements in the same group have equal valency.
(ii) Valency depends upon the number of valence electrons in an atom.
(iii) Copper and zinc are transition elements.
(iv) Noble gases are placed at the extreme right of the periodic table.
7. Name 2 elements in each case:
(i) Alkali metals
(ii) Alkaline earth metals
(iii) Halogens
(iv) Inert gas
(v) Transition metals
(vi) Lanthanides
(vii) Actinides
Solution 7.
(i) Sodium and Potassium
(ii) Calcium and Magnesium
(iii) Chlorine and Bromine
(iv) Neon and Argon
(v) Iron and Cobalt
(vi) Cerium and Europium
(vii) Uranium and Neptunium
8. What do you understand by?
(i) Periodicity
(ii) Typical elements
(iii) Orbits
Solution 8.
9. Name 2 elements you would expect to show chemical reactions similar to calcium. What is the basis of your choice?
Solution 9.
10. Name the (i) metals, (ii) metalloids and (iii) non-metals in the first twenty elements.
Solution 10.
Solution 11.
12.What is the main characteristic of the last element in each period of the Periodic Table? What is the general name of such elements?
Solution 12.
Solution 13.
Solution 14.
15. Name the type of elements, which have their
(i) Outermost shell complete
(ii) Outermost shell incomplete
(iii) Two outermost shells incomplete
(iv) One electron short of octet
(v) Two electrons in the outermost orbit.
Solution 15.
(i) Noble gases
(ii) Representative elements
(iii) Transition elements
(iv) Halogens
(v) Alkaline Earth metals
16. An element has 2 electrons in its N shell
(i) What is its atomic number?
(ii) State its position in periodic table
(iii) Is it metal or non-metal?
(iv) State the name assigned to this group.
Solution 16.
(i) 30
(ii) It belongs to group 12 and fourth period.
(iii) It is a metal.
(iv) The name assigned to this group is IIB.
17.
Solution 17.
(i) Electronic configuration of P: 2,8,5
(ii) 15th Group and 3rd Period.
(iii) Valency of P = 8 – 5 = 3
(iv) Phosphorus is a non-metal.
(v) It is an oxidizing agent.
(vi) Formula with chlorine = PCl3
Solution 1.
2. Give the trends in atomic size on moving
(i) Down the group
(ii) Across the period left to right.
Solution 2.
(i) The atomic size of an atom increases when we go down a group from top to bottom.
(ii) It increases as we move from right to left in a period.
3. Arrange the elements of second and third period in increasing order of their atomic size.
Solution 3.
4. Why is the size of
(i) Neon greater than fluorine
(ii) Sodium is greater than magnesium.
Solution 4.
5. Which is greater in size
(i) An atom or a cation?
(ii) An atom or an anion?
(iii) Fe 2+ or Fe3+?
Solution 5.
6. Arrange :
Be, Li, C, B, N, O, F (in increasing metallic character)
Si, Na, Al, Mg, Cl, P, S (in decreasing non-metallic character)
Solution 6.
Solution 8.
9.
Solution 9.
(i) The metallic character decreases as we go from left to right in a period.
(ii) It increases as we go down a group.
10. An element X belong to 3rd period and 17th group, state
(i) no of valence electrons in it.
(ii) name of the element.
(iii) name the family to which it belongs.
(iv) write the formula of the compound formed when it reacts with
.
Solution 10.
(i) The element from the 17th group has 7 electrons in its outermost shell.
(ii) The name of the element is chlorine.
(iii) Chlorine belongs to the halogen family.
11. The given table shows elements with same number of electrons in its valence shell.
Solution 11.
(i) Yes, these elements belong to the same group but are not from the same period.
The metallic character increases as one moves down the group.
Hence, the order of the given elements with increasing metallic character is as follows:
B
12.
Solution 12.
The melting and boiling points of metals decrease on going down the group.
Example: Observe the trend in group 1 elements given in the following table:
13. Which one of the following has the largest atomic radius?
i. Sodium
ii. Potassium
iii. Magnesium
iv. Aluminium
Solution 13.
Correct option: (ii) Potassium
14. Which one has the largest size?
i. Br
ii. I
iii. I-
iv. Cl
Solution 14.
Correct option: (iii) I–
15. The metals of group 2 from top to bottom are Be, Mg, Ca, Sr and Ba.
Which one of these elements will form ions most readily and why?
State the common feature in their electronic configuration.
Solution 15.
16.
Solution 16.
17. The electronic configuration of an element T is 2, 8, 8, 1.
What is the group number of T?
What is the period number of T?
How many valence electrons are there in an atom of T?
What is the valency of T?
Is it a metal or a non-metal?
Solution 17.
18. The element barium has atomic number 56. Look up its position in the periodic table and answer the following questions:
(i) Is it a metal or a non-metal?
(ii) Is it more or less reactive than calcium?
(iii) What is its valency?
(iv) What will be the formula of its phosphate?
(v) Is it larger or smaller than caesium (Cs) in size?
Solution 18.
(i) It belongs to group II and has 2 valence electrons, so it is a metal.
(ii) Barium is placed below calcium in the group. Since the reactivity increases below the group, barium is more reactive than calcium.
(iii) It needs to lose 2 valence electrons to complete its octet configuration, so its valency is 2.
(iv) The formula of its phosphate will be Ba3 (PO4)2.
(v) As we move from left to right in a period, the size decreases, so it will be smaller than caesium.
19. In group I of the periodic table, three elements X,Y and Z have ionic radii 1.33
, 0.95 and 0.60 , respectively. Giving a reason, arrange them in the order of increasing atomic numbers in the group.
Solution 19.
20. Explain why are the following statements are not correct:
(i) All groups contain metal and non-metal.
(ii) Atoms of elements in the same group have same number of electron(s).
(iii) Non-metallic character decreases across a period with increase in atomic number.
(iv) Reactivity increases with atomic number in group as well as in a period.
Solution 20.
21. Match the atomic number 19, 15, 8, 4 and 2 with each of the following:
(i) A metal of valency one
(ii) A solid non-metal of period 3
(iii) A rare gas
(iv) A gaseous element with valency 2
(v) An element of group 2
Solution 21.
(i) A metal of valency one = 19
(ii) A solid non-metal of period 3 = 15
(iii) A rare gas = 2
(iv) A gaseous element with valency 2 = 8
(v) An element of group 2 = 4
22. Complete the following sentences choosing the correct word or words from those given in brackets at the end of each sentence:
The properties of the elements are a periodic function of their _____ (atomic number, mass number, relative atomic mass).
Moving across a _____ of the periodic table, the elements show increasing _____ character (group, period, metallic, non-metallic).
The elements at the bottom of a group would be expected to show _____ metallic character than the element at the top (less, more).
The similarities in the properties of a group of elements are because they have the same _____ (electronic configuration, number of outer electrons, atomic numbers).
Solution 22.
23.(i).Give reasons for the following:
The size of a Cl- ion is greater than the size of a Cl atom.
Solution 23(i).
23.(ii). Give reasons for the following:
Argon atom is bigger than chlorine atom.
Solution 23(ii).
The inert gas argon is the next element after chlorine in the third period.
23.(iii). Give reasons for the following:
Ionisation potential of the element increases across a period.
Solution 23(iii).
23.(iv).
Solution 23(iv).
Alkali metals are strong reducing agents because they lose electrons easily to complete their octet.
24.(i). Name the element which has:
two shells, both of which are completely filled with electrons?
Solution 24(i).
Neon (Atomic number = 10)
Electronic configuration = 1s22s22p6
24.(ii). Name the element which has:
the electronic configuration 2, 8, 3?
Solution 24(ii).
Electronic configuration = 2, 8, 3
Hence, atomic number = 13
The element having atomic number 13 is Aluminium.
24.(iii). Name the element which has:
a total of three shells with five electrons in its valence shell?
Solution 24(iii).
The element has a total of three shells; hence, the element belongs to the third period.
Five valence electrons indicate that the element belongs to the fifth group (VA).
Hence, the element is phosphorus.
24.(iv). Name the element which has:
a total of four shells with two electrons in its valence shell.
Solution 24(iv).
The element has a total of four shells; hence, the element belongs to the fourth period.
Two valence electrons indicate that the element belongs to the second group (IIA).
Hence, the element is calcium.
24.(v). Name the element which has:
twice as many electrons in its second shell as in its first shell?
Solution 24(v).
We know that
Number of electrons = Number of protons = Atomic number
The element with atomic number 4 is beryllium.
25.(i). State the number of elements in Period 1, Period 2 and Period 3 of the periodic table. Name them.
Solution 25(i).
Period 1:
Number of elements = 2
Hydrogen, helium
Period 2:
Number of elements = 8
Lithium, beryllium, boron, carbon, nitrogen, oxygen, fluorine, neon
Period 3:
Number of elements = 8
Sodium, magnesium, aluminium, silicon, phosphorus, sulphur, chlorine, argon
25.(ii). What is the common feature of the electronic configuration of the elements at the end of Period 2 and Period 3?
Solution 25(ii).
25.(iii). If an element is in Group 17, it is likely to be ______ [metallic/non-metallic] in character, while with one electron in its outermost energy level (shell), then it is likely to be _______ [metallic/non-metallic].
Solution 25(iii).
1(a) Define the term 'ionization potential'.
(b) Represent it in the form of an equation. In which unit it is measured?
Solution 1.
M can be any element
It is measured in electron volts per atom. Its S.I unit kJmol-1.
2. Ionisation Potential values depend on
a. atomic size
b. nuclear pull. Explain.
Solution 2.
Ionisation potential values depend on
4. Name the elements with highest and lowest ionization energies in first three periods
Solution 4.
5. Arrange the elements of second and third period in increasing order of ionization energy.
Solution 5.
6.(a) Define the term electron affinity.
(b) Arrange the elements of second period in increasing order of electron affinity. Name the elements which do not follow the trend in this period.
Solution 6(2010).
Second period: Lithium<Boron < Carbon < Oxygen < Fluorine
Neon, Nitrogen and Beryllium do not follow the trend.
7. Electron affinity values generally ----- across the period left to right and ------down the group top to bottom.
Solution 7.
Electron affinity values generally increase across the period left to right and decrease down the group top to bottom.
8.(a). Define the term 'Electronegativity'. State its unit.
Solution 8(a).
8.(b). Among the elements given below, the element with least electronegativity is
(i) Lithium, (ii) Boron, (iii) Carbon, (iv) Fluorine
Solution 8(b).
Correct option – (i).
The element with least electronegativity is lithium.
9. Explain the following :
(a) Group 17 elements are strong non-metals, while group I elements are strong metals.
(b) Metallic character of elements decreases from left to right in a period while it increases in moving down a group.
(c) Halogens have a high electron affinity.
(d) The reducing power of element increases down in the group while decreases in a period.
(e) Size of atoms progressively becomes smaller when we move from sodium (Na) to chlorine (Cl) in the third period of the periodic Table.
Solution 9.
10. Name the periodic property which relates tothe
(i) Amount of energy required to remove an electron from an isolated gaseous atom.
(ii) Character of element which loses one or more electrons when supplied with energy.
(iii) Tendency of an atom to attract the shared pair of electrons.
Solution 10.
(i) Ionization energy
(ii) Metallic character
(iii) Electronegativity
11. This question refers to the elements of the periodic table with atomic numbers from 3 to 18. Some of the elements are shown by letters, but the letters are not the usual symbols of the elements.
3 4 5 6 7 8 9 10
A B C D E F G H
11 12 13 14 15 16 17 18
I J K L M N O P
Which of these
are the most electronegative element
is a halogen
is an alkali metal
is an element with valency 4
have least ionisation energy
have least atomic size in Period 3
Solution 11.
(a) G (due to the smallest atomic size).
(b) G and O as both have outermost electronic configuration np5.
(c) A and I as both have outermost electronic configuration ns1.
(d) D (1s22s22p2)
12. A group of elements in the Periodic Table are given below (boron is the first member of the group and thallium is the last).
Boron, Aluminium, Gallium, Indium, Thallium
Answer the following questions in relation to the above group of elements:
(a) Which element has the most metallic character?
(b) Which element would be expected to have the highest electronegativity?
(c) If the electronic configuration of aluminium is 2,8,3, how many electrons are there in the outer shell of thallium?
(d) The atomic number of boron is 5. Write the chemical formula of the compound formed when boron reacts with chlorine.
(e) Will the elements in the group to the right of this boron group be more metallic or less metallic in character? Justify your answer.
Solution 12.
13.
Solution 13.
14.
Solution 14.
15.
Solution 15.
16.
Solution 16.
Solution a(2015)
a(2009).
Solution a(2009)
Correct option is A. Lithium
Correct option is A. Lithium
b(2009).Group No.'s
Solution b(2009)
a(2010). The number of electrons in the valence shell of a halogen is ………. A - 1, B - 3, C - 5, D - 7.
Solution a(2010)
The number of electrons in the valence shell of a halogen is 7.
Correct option: D
b(2010). Electronegativity across the period ............ [increases/decreases].
Solution b(2010)
Electronegativity across the period increases.
c(2010). Non-metallic character down the group ………… [increases/decreases].
Solution c(2010)
Non-metallic character down the group decreases.
d(2010). Atomic number of an element is 16. State
to which period it belongs
the number of valence electrons in the element
is the element metal or non-metal
Solution d(2010)
Atomic number of an element is 16.
Solution a(2011)
Solution (b)2011
Solution c(i)(2011)
In the periodic table, alkali metals are placed in Group I. So, the correct option is A.
c(ii)(2011) Choose the correct answer from the choice given:
Which of the following properties do not match with elements of the halogen family?
a. They have seven electrons in their valence shell.
b. They are highly reactive chemically.
c. They are metallic in nature.
d. They are diatomic in their molecular form.
Solution c(ii)(2011)
The correct option is C.
The elements of halogen family are non-metallic in nature.
d(2011). State the group and period of the element having three shells with three electrons in the valence shell.
Solution (d)2011
Three shells indicate that the element belongs to the third period.
Three valence electrons indicate that the element belongs to the third group.
a(2012). Choose the correct answer from the option:
An element in Period 3 whose electronic affinity is zero.
Neon
Sulphur
Sodium
Argon
Solution a(2012)
Correct option: (D) Argon
b(2012). Give reason:
Ionisation potential of the element increases across a period.
Alkali metals are good reducing agents.
Solution b(2012)
Solution c(2012)
Electronic configuration of E with atomic number 19 = 1s22s22p63s23p64s1
E is a metal.
Electronic configuration of F with atomic number 8 =
1s22s22p4
F is a non-metal.
Electronic configuration of G with atomic number 17 =
1s22s22p63s23p5
G is a non-metal.
d(2012). Name: A metal present in Period 3, Group I of the periodic table.
Solution d(2012)
A metal present in Period 3, Group I of the periodic table is sodium.
a(2013). Among the Period 2 elements, the element which has high electron affinity is
Lithium
Carbon
Chlorine
Fluorine
Solution a(2013)
Correct option: (D) Fluorine
b(2013).
Solution b(2013)
Solution c(2013)
The element which has the highest ionisation potential is helium (He).
a(2014).Choose the correct answer from the choice given:
i. Ionisation potential increases over a period from left to right because the
Atomic radius and nuclear charge increase
Atomic radius and nuclear charge decrease
Atomic radius increases and nuclear charge decreases
Atomic radius decreases and nuclear charge increases
ii. An element A belonging to Period 3 and Group II will have
3 shells and 2 valence electrons
2 shells and 3 valence electrons
3 shells and 3 valence electrons
2 shells and 2 valence electrons
Solution a (2014)
(i)State the period and group to which Z belongs.
(ii)Is Z a metal or a non-metal?
Solution b (2014)
(a) An element Z having atomic number 16 is Sulphur.
(i) Sulphur belongs to Period 3 and Group 16.
(ii) Sulphur is a non-metal.
c(2014). Give one word or phrase for: The amount of energy released when an atom in the gaseous state accepts an electron to form an anion.
Solution c (2014)
Electron affinity
d(2014). Match the option A and B with the statements (i) and (ii):
Solution d (2014)
A: (ii)
B: (i)
e(2014). M is a metal above hydrogen in the activity series and its oxide has the formula M2O. This oxide, when dissolved in water, forms the corresponding hydroxide which is a good conductor of electricity. In the above context, answer the following:
What kind of combination exists between M and O?
State the number of electrons in the outermost shell of M.
Name the group to which M belongs.
Solution e (2014)
1. Ionic bond exists between M and O.
2. 1 electron is present in the outermost shell of M.
3. M belongs to Group 1 in the modern periodic table.
1. Select the correct answer from the choices A, B, C, D which are given. Write down only the letter corresponding to correct answer.
With reference to the variation of properties in the Periodic table, which of the following is generally true?
A Atomic size increases from left to right across a period.
B Ionization potential increases from left to right across a period.
C Electron affinity increases going down a group.
D Electro-negativity increases going down a group.
Solution 1(2008)
B
2.
Solution 2
Solution 3 (2015)
a. Mg,Cl, Na, S, Si (increasing order of atomic size) –
Cl < S < Si < Mg < Na
99 pm < 104 pm < 117 pm < 160 pm < 186 pm
b. Cs, Na, Li, K, Rb (increasing metallic character)
Li < Na < K < Rb < Cs
c. Na, K,Cl, S, Si (increasing ionisation potential) –
Cl < S < Si < Na < K
1256 < 999 < 786 < 496 < 419
d. Cl, F, Br, I (increasing electron affinity) –
I < Br < F < Cl
-295 KJ mol-1 < -324 KJ mol-1 < -327.9 KJ mol-1 < -349 KJ mol-1
e. Cs, Na, Li, K,Rb (decreasing electronegativity) –
Li > Na > K = Rb > Cs
1.0 > 0.9 > 0.8 = 0.8 > 0.7
4. Chorine in the periodic table is surrounded by the elements with atomic number 9, 16, 18 and 35.
(a) Which of these have physical and chemical properties resembling chlorine?
(b) Which is more electronegative than chlorine?
Solution 4
(a) An element with atomic number 9 and 35
(b) An element with atomic number 9.
5. First Ionization enthalpy of two elements X and Y are 500 kJ/mol-1 and 375 kJ /mol-1 respectively. Comment about their relative position in a group as well in a period.
Solution 5
Solution 6
(a) Cl < Cl¯
(b) Mg2+ < Mg+ < Mg
(c) O < N < P
7. Which element from the following has the highest ionization energy?
(a) P, Na, Cl
(b) F, O, Ne
(c) Ne, He, Ar
Explain your choice.
Solution 7
8. The electronegativities(according to Pauling) of the elements in period 3 of the periodic table are as follows with elements arranged in alphabetical order:
Solution 8
Na, Mg, Al, Si, P, S, Cl
9. Choose the word or phrase from the brackets which correctly completes each of the following statements:
The element below sodium in the same group would be expected to have a ............... (lower/higher) electro-negativity than sodium, and the element above chlorine would be expected to have a (lower/higher) ionisation potential than chlorine.
On moving from left to right in a given period, the number of shells ................. (remains the same/increases decreases).
On moving down a group, the number of valence electrons .................. (remains the same/increases/decreases).
Metals are good ................. (oxidising agents/reducing agents) because they are electron ............. (acceptors/donors).
Solution 9 (2016)
(c) On moving down a group, the number of valence electrons remains the same.
(d) Metals are good reducing agents because they are electron donors.
10. Parts (a) to (e) refer to change in the properties of elements on moving from left to right across a period of the periodic table. For each property, choose the correct answer.
(a) The non-metallic character of the elements:
(i) Decreases
(ii) Increases
(iii) Remains the same
(iv) Depends on the period
(b) The electronegativity:
(i) Depends on the number of valence electrons
(ii) Remains the same
(iii) Decreases
(iv) Increases
(c) The ionization potential:
(i) goes up and down
(ii) Decreases
(iii) Increases
(iv) Remains the same
(d) The atomic size:
(i) Decreases
(ii) Increases
(iii) Remains the same
(iv) Sometimes increases and sometimes decreases
(e) The electron affinity of elements in group 1 to 7 :
(i) Goes up and then down
(ii) Decreases and then increases
(iii) Increases
(iv) Decreases
Solution 10.
(a) Increases
(b) Increases
(c) Increases
(d) Decreases
(e) Increases
11. The elements of one short period of the periodic table are given below in order from left to right:
Li Be B C O F Ne
(a) To which period do these elements belong?
(b) One element of this period is missing. Which is the missing element and where should it be placed?
(c) Place the three elements: Fluorine, Beryllium and nitrogen in the order of increasing electronegativity.
(d) Which one of the above element belongs to the halogen series?
Solution 11.
(a) Period 2
(b) Nitrogen (N), between carbon and oxygen
(c) Be< N< F
(d) Fluorine
12. Name an
(a) An alkali metal in period 3 and halogen in period 2
(b) The noble gas with 3 shells
(c) The non-metals present in period 2 and metals in period 3.
(d) The element of period 3 with valency 4.
(e) The element in period 3 which does not form an oxide.
(f) The element of lower nuclear charge out of Be and Mg.
(g) Which has higher E.A. Fluorine or Neon?
(h) Which has maximum metallic character Na, Li or K?
Solution 12.
(a) Na and F
(b) Argon
(c) C, N, O and F are non-metals present in period 2 while Na, Mg and Al are metals in period 3.
(d) Silicon
(e) Argon
(f) Mg
(g) Fluorine
(h) K
13.
Solution 13.
Hence, number of protons in K atom = 19
Number of neutrons = Mass number – Atomic number
Hence, number of neutrons in K atom = 39-19 = 20
Number of electrons = Number of protons
Hence, number of electrons= 19
And electronic configuration of K atom = 2, 8, 8, 1
Since K atom has 4 shells, hence it belongs to fourth period.
With one valence electron, it belongs to group 1
Number of protons in P atom = 15
Number of neutrons in P atom = 31-15 = 16
Number of electrons in P atom = 15
And electronic configuration of P atom = 2, 8, 5
14.
Solution 14.
15.
Solution 15.
16.
Solution 16.
The electronic configuration of an element determines its position in Modern Periodic table.
17.
Solution 17.
Solution 18.
(a) Periods
(b) Increases
(c) Decreases
19.
Solution 19.
Solution 20.
21.
Solution 21.
(a) Noble gases- H and P
(b) Halogens- G and O
(c) Alkali metals – A and I
(d) D and L have valency of 4
(e) I with atomic number 11.
(f) Cl has the least atomic size in period 3 with atomic number 17.
22.
Solution 22.
As we move down a group, the numbers of shells increases and hence the atomic size increases.
23.
Solution 23.
24.
Solution 24.
(c) Since it has electronic configuration of 2, 8, 2, its atomic number is 12 and hence X is Magnesium.
(d) It is a metal.
25.
Solution 25.
(a) Group 1since the valence electrons is 1.
(b) With 4 shells T belong to period 4.
(c) Number of electrons = 2+8+8+1=19
(d) T needs to lose one electron to complete its octet hence its valency is 1.
(e) Since it has one valence electron, it is a metal.
26.
Solution 26.
(a) Group 1: Lithium< Sodium< Potassium< Rubidium < Caesium< Francium
Group 17: Fluorine < Chlorine < Bromine< Iodine < Astatine
(b) Group 1: Francium
Group 17: Astatine< Iodine< Bromine< Chlorine< Fluorine
(c) Group 1: Francium< Cesium< Rubidium< Potassium< Sodium< Lithium
Group 17: Astatine< Iodine< Bromine< Chlorine< Fluorine
(d) Group 1: Francium
Group 17: Astatine
(e) Group 1: Lithium>Sodium> Potassium> Rubidium> Cesium> Francium
Group 17: Fluorine > Chlorine> Bromine > Iodine > Astatine
27.
Solution 27.
(a) atomic number
(b) period, non-metallic character
(c) more
(d) number of outer electrons
28.
Solution 28.
(a) Neon
(b) Aluminum
(c) Phosphorus
(d) Calcium
(e) Carbon
30. Name an
(a) An alkali metal in period 3 and halogen in period 2
(b) The noble gas with 3 shells
(c) The non-metals present in period 2 and metals in period 3.
(d) The element of period 3 with valency 4.
(e) The element in period 3 which does not form an oxide.
(f) The element of lower nuclear charge out of Be and Mg.
(g) Which has higher E.A. Fluorine or Neon?
(h) Which has maximum metallic character Na, Li or K?
Solution 30.
(a) Na and F
(b) Argon
(c) C, N, O and F are non-metals present in period 2 while Na, Mg and Al are metals in period 3.
(d) Silicon
(e) Argon
(f) Mg
(g) Fluorine
(h) K
31. Chorine in the periodic table is surrounded by the elements with atomic number 9, 16, 18 and 35.
(a) Which of these have physical and chemical properties resembling chlorine?
(b) Which is more electronegative than chlorine?
Solution 31.
(a) Element with atomic number 9 and 35
(b) Element with atomic number 9.
32.
Solution 32.
(a) Period 1 has 2 elements while period 2 and period 3 have 8 elements each.
(b) Hydrogen and helium
(c) The elements at the end of period 2 and Period 3 have 8 electrons in its outermost shell.
(d) Non metallic, metallic.
33.
Solution 33.
Position in a group: X and Y
Position in a period: Y and X
34.
Solution 34.
Period no. = no. of shells, so n=3
From the formula M2 O3 its valency is 3.
Since it is a metal, its valence shell has 3 electrons.
So its electronic configuration is 2,8,3
Atomic number=13
Hence the metal is Aluminum with valency 3.
35.
Solution 35.
36.Arrange the following in order of increasing radii:
Solution 36.
(a) Cl < Cl¯
(b) Mg2+ < Mg+ < Mg
(c) O < N < P
37. Which element from the following has the highest ionization energy?
(a) P, Na, Cl
(b) F, O, Ne
(c) Ne, He, Ar
Explain your choice.
Solution 37.
38.
Solution 38.
(a) (iv) Argon
(b) (iii) Calcium
(c) (iii) Helium
1(2003).
Solution 1 (2003).
(a) (Al)2(SO4)3
(b) Covalent bonding
(c) Same number of valence electrons
(d) Helium
(e) 8
(f) Electron affinity
(g) Decreases, atomic number, number of shells
1(2004).(a). The electronegativities(according to Pauling) of the elements in period 3 of the periodic table are as follows with elements arranged in alphabetical order:
Solution 1 (2004).
(a) Na, Mg, Al, Si, P, S, Cl
(b)
(i) Lower, higher
(ii) remains the same
(iii) remains the same
1(2005). Parts (a) to (e) refer to change in the properties of elements on moving from left to right across a period of the periodic table. For each property, choose the correct answer.
(a) The non-metallic character of the elements:
(i) Decreases
(ii) Increases
(iii) Remains the same
(iv) Depends on the period
(b) The electronegativity:
(i) Depends on the number of valence electrons
(ii) Remains the same
(iii) Decreases
(iv) Increases
(c) The ionization potential:
(i) goes up and down
(ii) Decreases
(iii) Increases
(iv) Remains the same
(d) The atomic size:
(i) Decreases
(ii) Increases
(iii) Remains the same
(iv) Sometimes increases and sometimes decreases
(e) The electron affinity of elements in group 1 to 7 :
(i) Goes up and then down
(ii) Decreases and then increases
(iii) Increases
(iv) Decreases
Solution 1 (2005).
(a) Increases
(b) Increases
(c) Increases
(d) Decreases
(e) Increases
1(2006). The elements of one short period of the periodic table are given below in order from left to right:
Li Be B C O F Ne
(a) To which period do these elements belong?
(b) One element of this period is missing. Which is the missing element and where should it be placed?
(c) Place the three elements: Fluorine, Beryllium and nitrogen in the order of increasing electronegativity.
(d) Which one of the above element belongs to the halogen series?
Solution 1 (2006).
(a) Period 2
(b) Nitrogen (N), between carbon and oxygen
(c) Be < N < F
(d) Fluorine
Solution 1 (2007).
(a) Thallium has the most metallic character since metallic character increases down the group.
(b) Boron has the highest electronegativity since it has the smallest size in the group.
(c) 3. Since all the elements in a group have same number of valence electrons.
(d) BCl3
(e) The elements in the group to the right of boron group would be less metallic as with the decrease in size and increase in atomic number, it will be more difficult for them to lose electrons.
(a) The modern periodic law states that “The properties of elements are the periodic functions of their atomic number.” Henry Moseley put forward the modern periodic law.
(b) A tabular arrangement of the elements in groups (vertical columns) and periods (horizontal rows) highlighting the regular trends in properties of elements is called a Periodic Table. Modern Periodic table has 7 periods and 18 groups.
2. Elements of group 1 and elements of group 17 both have valency1. Explain.
Valency is the combining capacity of the atom of an element. It is equal to the number of electrons an atom can donate or accept or share. It is just a number and does not have a positive or negative sign.
Group 1elements have 1 electron in their outermost orbital, while Group 7 elements have 7 electrons in their outermost orbital.
Valency depends on the number of electrons in the outermost shell (i.e. valence shell).
Valency depends on the number of electrons in the outermost shell (i.e. valence shell).
If the number of electrons present in the outermost shell is 1, then it can donate one electron while combining with other elements to obtain a stable electronic configuration.
If the number of electrons present in the outermost shell is 7, then its valency is again 1 (8 – 7 = 1) as it can accept 1 electron from the combining atom.
In a given period, the number of electrons in the valence (outermost) shell increases from left to right. But the valency increases only up to Group 14, where it becomes 4, and then it decreases, that is, it becomes 1 in Group 17.
3. What are horizontal rows and vertical columns in a periodic table known as?
3. What are horizontal rows and vertical columns in a periodic table known as?
Solution 3.
The horizontal rows are known as periods and vertical columns in the periodic table are known as groups.
4. Periodicity is observed due to the similar.............
(number of valence electrons/ atomic number/ electronic configuration)
Solution 4.
Periodicity is observed due to the similar electronic configuration..
5. How does electronic configuration in atoms change
(i) In a period from left to right?
(ii) In a group top to bottom?
Solution 5.
(i) Though the number of shells remain the same, number of valence electrons increases by one, as we move across any given period from left to right.
(ii) While going from top to bottom in a group, the number of shells increases successively i.e. one by one but the number of valence electrons remains the same.
6. Correct the statements.
(i) Elements in the same period have equal valency.
(ii) Valency depends upon the number of shells in an atom.
(iii) Copper and zinc are representative elements.
(iv) Transition elements are placed at the extreme right of the periodic table.
(i) Elements in the same group have equal valency.
(ii) Valency depends upon the number of valence electrons in an atom.
(iii) Copper and zinc are transition elements.
(iv) Noble gases are placed at the extreme right of the periodic table.
7. Name 2 elements in each case:
(i) Alkali metals
(ii) Alkaline earth metals
(iii) Halogens
(iv) Inert gas
(v) Transition metals
(vi) Lanthanides
(vii) Actinides
Solution 7.
(i) Sodium and Potassium
(ii) Calcium and Magnesium
(iii) Chlorine and Bromine
(iv) Neon and Argon
(v) Iron and Cobalt
(vi) Cerium and Europium
(vii) Uranium and Neptunium
8. What do you understand by?
(i) Periodicity
(ii) Typical elements
(iii) Orbits
Solution 8.
(i) The properties that reappear at regular intervals, or in which there is a gradual variation at regular intervals, are called periodic properties and the phenomenon is known as the periodicity of elements.
(ii) The third period elements, Na, Mg, Al, Si, P and Cl summarize the properties of their respective groups and are called typical elements.
(iii) The elements of the second period show resemblance in properties with the elements of the next group of the third period leading to a diagonal relationship. Such elements are called bridge elements.
9. Name 2 elements you would expect to show chemical reactions similar to calcium. What is the basis of your choice?
Beryllium and magnesium will show similar chemical reactions as calcium. Since these elements belong to same group 2 and also have two electrons in their outermost shell like calcium.
10. Name the (i) metals, (ii) metalloids and (iii) non-metals in the first twenty elements.
Solution 10.
- Metals: Lithium, Beryllium, Sodium, Magnesium, Aluminium, Potassium, Calcium
- Metalloids: Boron, Silicon
- Non-metals: Hydrogen, Helium, Carbon, Nitrogen, Oxygen, Fluorine, Neon, Phosphorous, Sulphur, Chlorine, Argon
11. Fluorine, Chlorine and Bromine are put in one group on the basis of their similar properties.
(i) What are those similar properties?
(ii) What is the common name of this group or family?
(i) What are those similar properties?
(ii) What is the common name of this group or family?
(i) Properties: Non-metallic, highest electronegativity in the respective periods, highest ionisation potentials in the respective periods, highest electron affinity in the respective periods.
(ii) Salt-forming; hence, the common name is halogens.
12.What is the main characteristic of the last element in each period of the Periodic Table? What is the general name of such elements?
The main characteristic of the last element in each period of the periodic table is they are inert or chemically unreactive.
The general name of such elements is ‘Noble gases’.
13. According to atomic structure, what determines which element will be the first and which will be the last in a period?
13. According to atomic structure, what determines which element will be the first and which will be the last in a period?
According to atomic structure, the number of valence electrons determines the first and the last element in a period.
14.
14.
Solution 14.
15. Name the type of elements, which have their
(i) Outermost shell complete
(ii) Outermost shell incomplete
(iii) Two outermost shells incomplete
(iv) One electron short of octet
(v) Two electrons in the outermost orbit.
Solution 15.
(i) Noble gases
(ii) Representative elements
(iii) Transition elements
(iv) Halogens
(v) Alkaline Earth metals
16. An element has 2 electrons in its N shell
(i) What is its atomic number?
(ii) State its position in periodic table
(iii) Is it metal or non-metal?
(iv) State the name assigned to this group.
Solution 16.
(i) 30
(ii) It belongs to group 12 and fourth period.
(iii) It is a metal.
(iv) The name assigned to this group is IIB.
17.
Solution 17.
(i) Electronic configuration of P: 2,8,5
(ii) 15th Group and 3rd Period.
(iii) Valency of P = 8 – 5 = 3
(iv) Phosphorus is a non-metal.
(v) It is an oxidizing agent.
(vi) Formula with chlorine = PCl3
Exercise Intext 2
1. What do you understand by atomic size? State its unit.
Atomic size is the distance between the centre of the nucleus of an atom and its outermost shell.
It’s measured in Angstrom and Picometre.2. Give the trends in atomic size on moving
(i) Down the group
(ii) Across the period left to right.
Solution 2.
(i) The atomic size of an atom increases when we go down a group from top to bottom.
(ii) It increases as we move from right to left in a period.
3. Arrange the elements of second and third period in increasing order of their atomic size.
Solution 3.
Second Period: Fluorine <Neon< Oxygen< Nitrogen < Carbon < Boron< Beryllium < Lithium.
Third Period: Chlorine < Argon < Sulphur < Phosphorus < Silicon < Aluminum < Magnesium < Sodium.
4. Why is the size of
(i) Neon greater than fluorine
(ii) Sodium is greater than magnesium.
Solution 4.
(i) The size of Neon is bigger compared to fluorine because the outer shell of neon is complete(octet).As a result, the effect of nuclear pull over the valence shell electrons cannot be seen. Hence the size of Neon is greater than fluorine.
(ii) Since atomic number of magnesium is more than sodium but the numbers of shells are same, the nuclear pull is more in case of Mg atom. Hence its size is smaller than sodium.
5. Which is greater in size
(i) An atom or a cation?
(ii) An atom or an anion?
(iii) Fe 2+ or Fe3+?
(i) An atom is always bigger than cation since cation is formed by the loss of electrons; hence protons are more than electrons in a cation. So the electrons are strongly attracted by the nucleus and are pulled inward.
(ii) An anion is bigger than an atom since it is formed by gain of electrons and so the number of electrons are more than protons. The effective positive charge in the nucleus is less, so less inward pull is experienced. Hence the size expands.
(iii) Fe 2+ is bigger than Fe3+ since Fe 2+ has more number of electrons than Fe3+ and hence the inner pull by nucleus is less strong on it as compared to the pull on Fe3+.
6. Arrange :
Be, Li, C, B, N, O, F (in increasing metallic character)
Si, Na, Al, Mg, Cl, P, S (in decreasing non-metallic character)
- In increasing metallic character: F < O < N < C < B < Be < Li
- In decreasing non-metallic character: Cl > S > P > Si > Al > Mg > Na
7. State the trends in chemical reactivity:
(i) Across the period left to right
(ii) Down the group
(i) Across the period left to right
(ii) Down the group
Solution 7.
(i) Across a period, the chemical reactivity of elements first decreases and then increases.
(ii) Down the group, chemical reactivity increases as the tendency to lose electrons increases down the group.
8.
8.
The periodic variation in electronic configuration as one move sequentially in increasing order of atomic number produces a periodic variation in properties.
As the elements are arranged in increasing order of atomic number, the metals with tendency to lose electrons are placed on the left and the metallic character decreases from left to right and increases down a group and non-metals with tendency to gain electrons are placed automatically on the right and the non-metallic character increase across a period and decreases down a group.
9.
Solution 9.
(i) The metallic character decreases as we go from left to right in a period.
(ii) It increases as we go down a group.
10. An element X belong to 3rd period and 17th group, state
(i) no of valence electrons in it.
(ii) name of the element.
(iii) name the family to which it belongs.
(iv) write the formula of the compound formed when it reacts with
.Solution 10.
(i) The element from the 17th group has 7 electrons in its outermost shell.
(ii) The name of the element is chlorine.
(iii) Chlorine belongs to the halogen family.
(iv) The element has 13Y27 three electrons in its outermost shell which it can donate; hence, its valency is three. While the valency of chlorine is 1. Thus, 13Y27 which is Aluminium can donate three electrons, and chlorine can accept 1 electron to get the stable electronic configuration.
Therefore, the formula of the compound is AlCl3.11. The given table shows elements with same number of electrons in its valence shell.
Elements | A | B | C |
m.p | 63.0 | 180.0 | 97.0 |
State :
(i) Whether these elements belong to same group or period.
(ii) Arrange them in order of increasing metallic character.
Solution 11.
(i) Yes, these elements belong to the same group but are not from the same period.
(ii) We know that m.p. decreases on going down the group. Hence, from the above table, the elements can be ordered according to their period as follows:
The metallic character increases as one moves down the group.
Hence, the order of the given elements with increasing metallic character is as follows:
B
12.
Solution 12.
The melting and boiling points of metals decrease on going down the group.
Example: Observe the trend in group 1 elements given in the following table:
13. Which one of the following has the largest atomic radius?
i. Sodium
ii. Potassium
iii. Magnesium
iv. Aluminium
Solution 13.
Correct option: (ii) Potassium
14. Which one has the largest size?
i. Br
ii. I
iii. I-
iv. Cl
Solution 14.
Correct option: (iii) I–
15. The metals of group 2 from top to bottom are Be, Mg, Ca, Sr and Ba.
Which one of these elements will form ions most readily and why?
State the common feature in their electronic configuration.
Solution 15.
(i) Barium will form ions most readily as the outermost valence electron which experiences the least force of attraction by positively charged nucleus can be given away readily to form cations.
(ii) All Group II elements have two valence electrons.16.
Solution 16.
17. The electronic configuration of an element T is 2, 8, 8, 1.
What is the group number of T?
What is the period number of T?
How many valence electrons are there in an atom of T?
What is the valency of T?
Is it a metal or a non-metal?
Solution 17.
- Group = 1
- Period = 4
- Valence electrons = 1
- Valency = 1
- Metal
18. The element barium has atomic number 56. Look up its position in the periodic table and answer the following questions:
(i) Is it a metal or a non-metal?
(ii) Is it more or less reactive than calcium?
(iii) What is its valency?
(iv) What will be the formula of its phosphate?
(v) Is it larger or smaller than caesium (Cs) in size?
Solution 18.
(i) It belongs to group II and has 2 valence electrons, so it is a metal.
(ii) Barium is placed below calcium in the group. Since the reactivity increases below the group, barium is more reactive than calcium.
(iii) It needs to lose 2 valence electrons to complete its octet configuration, so its valency is 2.
(iv) The formula of its phosphate will be Ba3 (PO4)2.
(v) As we move from left to right in a period, the size decreases, so it will be smaller than caesium.
19. In group I of the periodic table, three elements X,Y and Z have ionic radii 1.33
, 0.95 and 0.60 , respectively. Giving a reason, arrange them in the order of increasing atomic numbers in the group.Solution 19.
Sincethe size of the atom increases down the group, the ionic radii will also increase. Hence, the order of increasing atomic numbers in the group is Z < Y < X.
20. Explain why are the following statements are not correct:
(i) All groups contain metal and non-metal.
(ii) Atoms of elements in the same group have same number of electron(s).
(iii) Non-metallic character decreases across a period with increase in atomic number.
(iv) Reactivity increases with atomic number in group as well as in a period.
Solution 20.
(i) All groups do not contain both metals and non-metals. Group I and II contain only metals.
(ii) Atoms of elements in the same group have same number of valence electrons. They have same number of electrons present in their outermost shell.
(iii) The non-metallic character increases across a period with increase in atomic number. This is because across the period, the size of atom decreases and the valence shell electrons are held more tightly.
(iv) On moving from left to right in a period, the reactivity of elements first decreases and then increases, while in groups, chemical reactivity of metals increases going down the group whereas reactivity of non-metals is decreases down the group.
21. Match the atomic number 19, 15, 8, 4 and 2 with each of the following:
(i) A metal of valency one
(ii) A solid non-metal of period 3
(iii) A rare gas
(iv) A gaseous element with valency 2
(v) An element of group 2
(i) A metal of valency one = 19
(ii) A solid non-metal of period 3 = 15
(iii) A rare gas = 2
(iv) A gaseous element with valency 2 = 8
(v) An element of group 2 = 4
22. Complete the following sentences choosing the correct word or words from those given in brackets at the end of each sentence:
The properties of the elements are a periodic function of their _____ (atomic number, mass number, relative atomic mass).
Moving across a _____ of the periodic table, the elements show increasing _____ character (group, period, metallic, non-metallic).
The elements at the bottom of a group would be expected to show _____ metallic character than the element at the top (less, more).
The similarities in the properties of a group of elements are because they have the same _____ (electronic configuration, number of outer electrons, atomic numbers).
Solution 22.
(i) The properties of the elements are a periodic function of their atomic number.
(ii) Moving across a period of the periodic table, the elements show increasing non-metallic character.
(iii) The elements at the bottom of a group would be expected to show more metallic character than the elements at the top.
(iv) The similarities in the properties of a group of elements are because they have the same number of outer electrons.
23.(i).Give reasons for the following:
The size of a Cl- ion is greater than the size of a Cl atom.
An anion is formed by the gain of electrons. In the chloride ion, the number of electrons is more than the number of protons. The effective positive charge in the nucleus is less, so the less inward pull is experienced. Hence, the size expands.
23.(ii). Give reasons for the following:
Argon atom is bigger than chlorine atom.
Solution 23(ii).
The inert gas argon is the next element after chlorine in the third period.
In a period, the size of an atom decreases from left to right due to an increase in nuclear charge with an increase in the atomic number. However, the size of the atoms of inert gases is bigger than the previous atom of halogen in the respective period. This is because the outer shell of inert gases is complete. They have the maximum number of electrons in their outermost orbit; thus, electronic repulsions are maximum. Hence, the size of the atom of an inert gas is bigger.
23.(iii). Give reasons for the following:
Ionisation potential of the element increases across a period.
Solution 23(iii).
Ionisation potential of the element increases across a period because the atomic size decreases due to an increase in the nuclear charge, and thus, more energy is required to remove the electron(s).
23.(iv).
Solution 23(iv).
Alkali metals are strong reducing agents because they lose electrons easily to complete their octet.
24.(i). Name the element which has:
two shells, both of which are completely filled with electrons?
Solution 24(i).
Neon (Atomic number = 10)
Electronic configuration = 1s22s22p6
24.(ii). Name the element which has:
the electronic configuration 2, 8, 3?
Solution 24(ii).
Electronic configuration = 2, 8, 3
Hence, atomic number = 13
The element having atomic number 13 is Aluminium.
24.(iii). Name the element which has:
a total of three shells with five electrons in its valence shell?
Solution 24(iii).
The element has a total of three shells; hence, the element belongs to the third period.
Five valence electrons indicate that the element belongs to the fifth group (VA).
Hence, the element is phosphorus.
24.(iv). Name the element which has:
a total of four shells with two electrons in its valence shell.
Solution 24(iv).
The element has a total of four shells; hence, the element belongs to the fourth period.
Two valence electrons indicate that the element belongs to the second group (IIA).
Hence, the element is calcium.
24.(v). Name the element which has:
twice as many electrons in its second shell as in its first shell?
Solution 24(v).
Twice as many electrons in its second shell as in its first shell indicates electronic configuration 1s22s2.
From the electronic configuration, the total number of electrons is 4.We know that
Number of electrons = Number of protons = Atomic number
The element with atomic number 4 is beryllium.
25.(i). State the number of elements in Period 1, Period 2 and Period 3 of the periodic table. Name them.
Solution 25(i).
Period 1:
Number of elements = 2
Hydrogen, helium
Period 2:
Number of elements = 8
Lithium, beryllium, boron, carbon, nitrogen, oxygen, fluorine, neon
Period 3:
Number of elements = 8
Sodium, magnesium, aluminium, silicon, phosphorus, sulphur, chlorine, argon
25.(ii). What is the common feature of the electronic configuration of the elements at the end of Period 2 and Period 3?
Solution 25(ii).
A common feature of the electronic configuration of the elements at the end of Period 2 and Period 3 is that the atoms have 8 electrons in their outermost shell.
25.(iii). If an element is in Group 17, it is likely to be ______ [metallic/non-metallic] in character, while with one electron in its outermost energy level (shell), then it is likely to be _______ [metallic/non-metallic].
Solution 25(iii).
If an element is in Group 17, it is likely to be non-metallic in character, while with one electron in its outermost energy level (shell), then it is likely to be metallic.
Exercise Intext 3
1(a) Define the term 'ionization potential'.
(b) Represent it in the form of an equation. In which unit it is measured?
Solution 1.
(a) The energy required to remove an electron from a neutral isolated gaseous atom and convert it into a positively charged gaseous ion is called Ionization energy or ionization potential.
(b) M(g)+ I.E → M+(g) + e–M can be any element
It is measured in electron volts per atom. Its S.I unit kJmol-1.
2. Ionisation Potential values depend on
a. atomic size
b. nuclear pull. Explain.
Solution 2.
Ionisation potential values depend on
- Atomic size: The greater the atomic size, the lesser the force of attraction. Electrons of the outermost shell lie further away from the nucleus, so their removal is easier and the ionisation energy required is less.
- Nuclear charge: The greater the nuclear charge, greater is the attraction for the electrons of the outermost shell. Therefore, the electrons in the outermost shell are more firmly held because of which greater energy is required to remove them.
3. State the trends in ionization energy:
(a) across the period
(b) down the group
Solution 3.(a) across the period
(b) down the group
(a) Ionization energy increases as we move from left to right across a period as the atomic size decreases.
(b) Ionization energy decreases down a group as the atomic size increases.4. Name the elements with highest and lowest ionization energies in first three periods
Solution 4.
Helium has the highest ionization energy of all the elements while cesium has the lowest ionization energy.
5. Arrange the elements of second and third period in increasing order of ionization energy.
Solution 5.
Second period: Neon > Fluorine > Oxygen > Nitrogen > Carbon > Boron > Beryllium > Lithium
Third Period: Argon> Chlorine > Sulphur > Phosphorus > Silicon > Aluminum >Magnesium > Sodium6.(a) Define the term electron affinity.
(b) Arrange the elements of second period in increasing order of electron affinity. Name the elements which do not follow the trend in this period.
Solution 6(2010).
(a) Electron affinity is the energy released when a neutral gaseous atom acquires an electron to form an anion.
(b) Second period: LithiumSecond period: Lithium<Boron < Carbon < Oxygen < Fluorine
Neon, Nitrogen and Beryllium do not follow the trend.
7. Electron affinity values generally ----- across the period left to right and ------down the group top to bottom.
Solution 7.
Electron affinity values generally increase across the period left to right and decrease down the group top to bottom.
8.(a). Define the term 'Electronegativity'. State its unit.
Solution 8(a).
Electronegativity is the tendency of an atom in a molecule to attract the shared pair of electrons towards itself.
Electronegativity is a dimensionless property; hence, it has no unit.8.(b). Among the elements given below, the element with least electronegativity is
(i) Lithium, (ii) Boron, (iii) Carbon, (iv) Fluorine
Solution 8(b).
Correct option – (i).
The element with least electronegativity is lithium.
9. Explain the following :
(a) Group 17 elements are strong non-metals, while group I elements are strong metals.
(b) Metallic character of elements decreases from left to right in a period while it increases in moving down a group.
(c) Halogens have a high electron affinity.
(d) The reducing power of element increases down in the group while decreases in a period.
(e) Size of atoms progressively becomes smaller when we move from sodium (Na) to chlorine (Cl) in the third period of the periodic Table.
Solution 9.
(a) On moving across a period, nuclear pull increases because of the increase in atomic number, and thus, the atomic size decreases. Hence, elements cannot lose electrons easily. Hence, Group 17 elements are strong non-metals, while Group 1 elements are strong metals.
(b) On moving across a period, nuclear pull increases because of the increase in atomic number, and thus, the atomic size decreases. Hence, elements cannot lose electrons easily. Hence, Group 17 elements are strong non-metals, while Group 1 elements are strong metals. Down a group, the atomic size increases and the nuclear charge also increases. The effect of an increased atomic size is greater as compared to the increased nuclear charge. Therefore, metallic nature increases as one moves down a group, i.e. they can lose electrons easily.
(c) The atomic size of halogens is very small. The smaller the atomic size, the greater the electron affinity, because the effective attractive force between the nucleus and the valence electrons is greater in smaller atoms, and so the electrons are held firmly.
(d) The reducing property depends on the ionisation potential and electron affinity of the elements. In a period, from left to right in a horizontal row of the periodic table, the atomic size decreases and the nuclear charge increases, so the electron affinity and ionisation energy both increase. Hence, the tendency to lose electrons decreases across the period from left to right and thus the reducing property also decreases across the period from left to right.
The electron affinity and ionisation potential decreases along the group from top to bottom. Hence, the tendency to lose electrons increases, and thus, the reducing property also increases along the group from top to bottom.
(e) In a period, the size of an atom decreases from left to right. This is because the nuclear charge, i.e. the atomic number increases from left to right in the same period, thereby bringing the outermost shell closer to the nucleus. Therefore, considering the third period given above, it has been found that sodium is the largest in size, while chlorine is the smallest.
10. Name the periodic property which relates tothe
(i) Amount of energy required to remove an electron from an isolated gaseous atom.
(ii) Character of element which loses one or more electrons when supplied with energy.
(iii) Tendency of an atom to attract the shared pair of electrons.
Solution 10.
(i) Ionization energy
(ii) Metallic character
(iii) Electronegativity
11. This question refers to the elements of the periodic table with atomic numbers from 3 to 18. Some of the elements are shown by letters, but the letters are not the usual symbols of the elements.
3 4 5 6 7 8 9 10
A B C D E F G H
11 12 13 14 15 16 17 18
I J K L M N O P
Which of these
are the most electronegative element
is a halogen
is an alkali metal
is an element with valency 4
have least ionisation energy
have least atomic size in Period 3
Solution 11.
(a) G (due to the smallest atomic size).
(b) G and O as both have outermost electronic configuration np5.
(c) A and I as both have outermost electronic configuration ns1.
(d) D (1s22s22p2)
(e) I as alkali metals have least ionisation energy. Also, ionisation energy decreases with an increase in the atomic size that decreases on moving down the group.
(f) O, as halogens have the least atomic size.12. A group of elements in the Periodic Table are given below (boron is the first member of the group and thallium is the last).
Boron, Aluminium, Gallium, Indium, Thallium
Answer the following questions in relation to the above group of elements:
(a) Which element has the most metallic character?
(b) Which element would be expected to have the highest electronegativity?
(c) If the electronic configuration of aluminium is 2,8,3, how many electrons are there in the outer shell of thallium?
(d) The atomic number of boron is 5. Write the chemical formula of the compound formed when boron reacts with chlorine.
(e) Will the elements in the group to the right of this boron group be more metallic or less metallic in character? Justify your answer.
Solution 12.
(a) Thallium. Because the metallic character increases down the group, thallium will have the most metallic character.
(b) Boron. Electronegativity decreases down the group as the size increases; hence, boron will be the most electronegative atom.
(c) Three. The number of electrons present in the valence shell is the same for each group. Hence, all these elements and thallium will have 3 valence electrons.
(d) BCl3
(e) Since metallic character decreases from left to right and non-metallic character increases from left to right, elements in the group to the right of this boron group will be less metallic in character.
13.
(a) As we move from left to right the increase in atomic number and decrease in size results in a greater nuclear pull. As a result, the ability to attract the electrons increases, and so does the electron affinity.
But noble gases have complete stable octet configuration, hence their electron affinity is lower than halogens.
Hence halogens on extreme right have highest electron affinity in a period.
(b) Chlorine is smaller than sulphur with a bigger atomic number. Since its nuclear pull is more, hence its electron affinity is higher than sulphur.
14.
Since size of chlorine is bigger than fluorine hence the electrons being farther away from the nucleus experience a lesser force of attraction, hence electron negativity of chlorine is less than fluorine.
15.
Solution 15.
Electronegativity measures an atom’s tendency to attract shared pair of electrons towards itself.
Its S.I unit is Pauling unit.16.
Solution 16.
(i) The element fluorine has the highest electronegativity and Caesium has the lowest electronegativity.
(ii) The nature of oxides changes from basic to acidic as we move from left to right in third period. Hence sodium forms most basic oxide while oxide of Aluminum is amphoteric and oxides of phosphorus, sulphur and chlorine are progressively acidic.
Exercise 1
a(2005).
(i) Lithium
Reason: Electronegativity increases from left to right. Lithium is present on the left side of the periodic table; hence, it will be the least electronegative element.
Solution b(2015)
(i) Ba metal will form ions readily because the ionisationenergy decreases down the group as the size increases.
(ii) On moving down the group, the number of electrons in the outermost shell, i.e.valence electrons remain the same. So, the valency in a group remains the same, i.e. 2.
a(2009).
Solution a(2009)
Correct option is A. Lithium
In a period from left to right, electron affinity decreases as the non-metallic character increases.
Solution a(2009)Correct option is A. Lithium
In a period from left to right, electron affinity decreases as the non-metallic character increases.
b(2009).Group No.'s
IA | IIA | IIIA | IVA | VA | VIA | VIIA | 0 |
1 | 2 | 13 | 14 | 15 | 16 | 17 | 18 |
Li | D | O | J | Ne | |||
A | Mg | E | Si | H | K | ||
B | C | F | G | L |
Select from the table:
- Which is the most electronegative?
- How many valence electrons are present in G?
- Write the formula of the compound between B and H.
- In the compound between F and J, what type of bond will be formed?
- Draw the electron dot structure for the compound formed between C and K.
Solution b(2009)
- The most electronegative is J.
- Valence electrons present in G are 5.
- B contains 1 valence electron and H contains 6 valence electrons. So, the valency of B is +1 and the valency of H is – 2.
- In the compound between F and J, the type of bond formed will be covalent.
- The electron dot structure for the compound formed between C and K is
a(2010). The number of electrons in the valence shell of a halogen is ………. A - 1, B - 3, C - 5, D - 7.
Solution a(2010)
The number of electrons in the valence shell of a halogen is 7.
Correct option: D
b(2010). Electronegativity across the period ............ [increases/decreases].
Solution b(2010)
Electronegativity across the period increases.
c(2010). Non-metallic character down the group ………… [increases/decreases].
Solution c(2010)
Non-metallic character down the group decreases.
d(2010). Atomic number of an element is 16. State
to which period it belongs
the number of valence electrons in the element
is the element metal or non-metal
Solution d(2010)
Atomic number of an element is 16.
- It belongs to Period 3.
- The number of valence electrons in the element is 6.
- The element is a non-metal.
a(2011).Give reasons - The oxidising power of elements increases from left to right along a period.
The oxidising power of elements depends on the tendency to gain electrons which increases from left to right along a period due to increase in nuclear pull.
b(2011). Select the correct answer:
Across a period, the ionisation potential ………… [increases, decreases, remains same]
Down the group, electron affinity ………… [increases, decreases, remains same]
b(2011). Select the correct answer:
Across a period, the ionisation potential ………… [increases, decreases, remains same]
Down the group, electron affinity ………… [increases, decreases, remains same]
Solution (b)2011
- Across a period, the ionisation potential increases.
- Down the group, electron affinity decreases.
c(i)(2011) Choose the correct answer from the choice given:
In the periodic table, alkali metals are placed in the group A : 1, B : 11, C : 17, D : 18.
In the periodic table, alkali metals are placed in the group A : 1, B : 11, C : 17, D : 18.
In the periodic table, alkali metals are placed in Group I. So, the correct option is A.
c(ii)(2011) Choose the correct answer from the choice given:
Which of the following properties do not match with elements of the halogen family?
a. They have seven electrons in their valence shell.
b. They are highly reactive chemically.
c. They are metallic in nature.
d. They are diatomic in their molecular form.
Solution c(ii)(2011)
The correct option is C.
The elements of halogen family are non-metallic in nature.
d(2011). State the group and period of the element having three shells with three electrons in the valence shell.
Solution (d)2011
Three shells indicate that the element belongs to the third period.
Three valence electrons indicate that the element belongs to the third group.
a(2012). Choose the correct answer from the option:
An element in Period 3 whose electronic affinity is zero.
Neon
Sulphur
Sodium
Argon
Solution a(2012)
Correct option: (D) Argon
b(2012). Give reason:
Ionisation potential of the element increases across a period.
Alkali metals are good reducing agents.
Solution b(2012)
- Because the atomic radius decreases across a period. Due to this, attraction between the nucleus and the electron increases. This results in an increase in the ionisation potential.
- Alkali metals are good reducing agents because they have a greater tendency to lose electrons.
c(2012). There are three elements E, F, G with atomic numbers 19, 8 and 17 respectively.
Classify the above elements as metals and non-metals.
Classify the above elements as metals and non-metals.
Electronic configuration of E with atomic number 19 = 1s22s22p63s23p64s1
E is a metal.
Electronic configuration of F with atomic number 8 =
1s22s22p4
F is a non-metal.
Electronic configuration of G with atomic number 17 =
1s22s22p63s23p5
G is a non-metal.
d(2012). Name: A metal present in Period 3, Group I of the periodic table.
Solution d(2012)
A metal present in Period 3, Group I of the periodic table is sodium.
a(2013). Among the Period 2 elements, the element which has high electron affinity is
Lithium
Carbon
Chlorine
Fluorine
Solution a(2013)
Correct option: (D) Fluorine
b(2013).
Group No. | 1-1A | 2-IIA | 13-IIIA | 14-IVA | 15-VA | 16-VIA | 17-VIIA | 18-0 |
2nd period | Li | D | O | J | Ne | |||
3rd period | A | Mg | E | Si | H | M | ||
4th period | R | T | I | Q | U | Y |
In the above table, H does not represent hydrogen. Some elements are given in their own symbol and position in the periodic table while others are shown with a letter. Answer the following questions.
- Identify the most electronegative element.
- Identify the most reactive element of Group I.
- Identify the element from Period 3 with least atomic size.
- How many valence electrons are present in Q?
- Which element from group 2 would have the least ionisation energy?
- Identify the noble gas of the fourth period.
- In the compound between A and H, what type of bond would be formed and give its molecular formula.
Solution b(2013)
- I
- R
- M
- 5
- T
- Y
- Ionic bond will be formed and the molecular formula is A2H.
Solution c(2013)
The element which has the highest ionisation potential is helium (He).
a(2014).Choose the correct answer from the choice given:
i. Ionisation potential increases over a period from left to right because the
Atomic radius and nuclear charge increase
Atomic radius and nuclear charge decrease
Atomic radius increases and nuclear charge decreases
Atomic radius decreases and nuclear charge increases
ii. An element A belonging to Period 3 and Group II will have
3 shells and 2 valence electrons
2 shells and 3 valence electrons
3 shells and 3 valence electrons
2 shells and 2 valence electrons
Solution a (2014)
- Correct option: D (atomic radius decreases and nuclear charge increases)
- Correct option: A (3 shells and 2 valence electrons)
(i)State the period and group to which Z belongs.
(ii)Is Z a metal or a non-metal?
Solution b (2014)
(a) An element Z having atomic number 16 is Sulphur.
(i) Sulphur belongs to Period 3 and Group 16.
(ii) Sulphur is a non-metal.
c(2014). Give one word or phrase for: The amount of energy released when an atom in the gaseous state accepts an electron to form an anion.
Solution c (2014)
Electron affinity
d(2014). Match the option A and B with the statements (i) and (ii):
A. metal | (i) The metal that forms two types of ions |
B. iron | (ii) An element with electronic configuration 2, 8, 8, 3 |
Solution d (2014)
A: (ii)
B: (i)
e(2014). M is a metal above hydrogen in the activity series and its oxide has the formula M2O. This oxide, when dissolved in water, forms the corresponding hydroxide which is a good conductor of electricity. In the above context, answer the following:
What kind of combination exists between M and O?
State the number of electrons in the outermost shell of M.
Name the group to which M belongs.
Solution e (2014)
1. Ionic bond exists between M and O.
2. 1 electron is present in the outermost shell of M.
3. M belongs to Group 1 in the modern periodic table.
1. Select the correct answer from the choices A, B, C, D which are given. Write down only the letter corresponding to correct answer.
With reference to the variation of properties in the Periodic table, which of the following is generally true?
A Atomic size increases from left to right across a period.
B Ionization potential increases from left to right across a period.
C Electron affinity increases going down a group.
D Electro-negativity increases going down a group.
Solution 1(2008)
B
2.
Solution 2
- A covalent oxide of a metalloid. – SiO2 (Si is a metalloid)
- An oxide which when dissolved in water forms acid. – SO2 (SO2 + H2O → H2SO3)
- A basic oxide. – Na2O (Na2O + H2O → 2NaOH)
- An amphoteric oxide. – Al2O3 (shows both acidic and basic properties)
3(2015). Arrange the following as per instructions given in the brackets.
Mg, Cl, Na, S, Si (increasing order of atomic size)
Cs, Na, Li, K, Rb (increasing metallic character)
Na, K, Cl, S, Si (increasing ionisation potential)
Cl, F, Br, I (increasing electron affinity)
Cs, Na, Li, K, Rb (decreasing electronegativity)
Solution 3 (2015)
a. Mg,Cl, Na, S, Si (increasing order of atomic size) –
Cl < S < Si < Mg < Na
99 pm < 104 pm < 117 pm < 160 pm < 186 pm
b. Cs, Na, Li, K, Rb (increasing metallic character)
Li < Na < K < Rb < Cs
c. Na, K,Cl, S, Si (increasing ionisation potential) –
Cl < S < Si < Na < K
1256 < 999 < 786 < 496 < 419
d. Cl, F, Br, I (increasing electron affinity) –
I < Br < F < Cl
-295 KJ mol-1 < -324 KJ mol-1 < -327.9 KJ mol-1 < -349 KJ mol-1
e. Cs, Na, Li, K,Rb (decreasing electronegativity) –
Li > Na > K = Rb > Cs
1.0 > 0.9 > 0.8 = 0.8 > 0.7
4. Chorine in the periodic table is surrounded by the elements with atomic number 9, 16, 18 and 35.
(a) Which of these have physical and chemical properties resembling chlorine?
(b) Which is more electronegative than chlorine?
Solution 4
(a) An element with atomic number 9 and 35
(b) An element with atomic number 9.
5. First Ionization enthalpy of two elements X and Y are 500 kJ/mol-1 and 375 kJ /mol-1 respectively. Comment about their relative position in a group as well in a period.
Solution 5
The ionisation energy is the minimum energy required to remove the outermost electron from a gaseous neutral atom to form a cation.
Position in a group: X will be above Y ( because of ionisation energy decreases down the group )
Position in a period: X will be the right side of Y ( because ionisation energy increases from left to right)
6. Arrange the following in order of increasing radii:
6. Arrange the following in order of increasing radii:
(a) Cl¯, Cl
(b) Mg2+, Mg, Mg+
(c) N, O, P
Solution 6
(a) Cl < Cl¯
(b) Mg2+ < Mg+ < Mg
(c) O < N < P
7. Which element from the following has the highest ionization energy?
(a) P, Na, Cl
(b) F, O, Ne
(c) Ne, He, Ar
Explain your choice.
Solution 7
(a) Cl
Metals have low ionisation energy and non-metals have high ionisation energy. Also, across the period, ionisationenergy tends to increase. The elements P, Na and Cl belong to the third period. Na – Group 1, P – Group 15 and Cl – Group 17.
(b) Ne
Inert gases have zero electron affinity because of their stable electronic configuration.
(c) He
Ionisation energy decreases with an increase in the atomic size, i.e. it decreases as one moves down a group. Ne, He and Ar are inert gases. He – Period 1, Ne – Period 2 and Ar – Period 3.
8. The electronegativities(according to Pauling) of the elements in period 3 of the periodic table are as follows with elements arranged in alphabetical order:
Al | Cl | Mg | Na | P | S | Si |
1.5 | 3 | 1.2 | 0.9 | 2.1 | 2.5 | 1.8 |
Arrange the elements in the order in which they occur in the periodic table from left to right.
(The group 1 element first, followed by the group 2 element and so on, up to group 7).
Na, Mg, Al, Si, P, S, Cl
9. Choose the word or phrase from the brackets which correctly completes each of the following statements:
The element below sodium in the same group would be expected to have a ............... (lower/higher) electro-negativity than sodium, and the element above chlorine would be expected to have a (lower/higher) ionisation potential than chlorine.
On moving from left to right in a given period, the number of shells ................. (remains the same/increases decreases).
On moving down a group, the number of valence electrons .................. (remains the same/increases/decreases).
Metals are good ................. (oxidising agents/reducing agents) because they are electron ............. (acceptors/donors).
Solution 9 (2016)
(a) The element below sodium in the same group would be expected to have a lower electro-negativity than sodium, and the element above chlorine would be expected to have a higher ionisation potential than chlorine.
(b) On moving from left to right in a given period, the number of shells remains the same.(c) On moving down a group, the number of valence electrons remains the same.
(d) Metals are good reducing agents because they are electron donors.
10. Parts (a) to (e) refer to change in the properties of elements on moving from left to right across a period of the periodic table. For each property, choose the correct answer.
(a) The non-metallic character of the elements:
(i) Decreases
(ii) Increases
(iii) Remains the same
(iv) Depends on the period
(b) The electronegativity:
(i) Depends on the number of valence electrons
(ii) Remains the same
(iii) Decreases
(iv) Increases
(c) The ionization potential:
(i) goes up and down
(ii) Decreases
(iii) Increases
(iv) Remains the same
(d) The atomic size:
(i) Decreases
(ii) Increases
(iii) Remains the same
(iv) Sometimes increases and sometimes decreases
(e) The electron affinity of elements in group 1 to 7 :
(i) Goes up and then down
(ii) Decreases and then increases
(iii) Increases
(iv) Decreases
Solution 10.
(a) Increases
(b) Increases
(c) Increases
(d) Decreases
(e) Increases
11. The elements of one short period of the periodic table are given below in order from left to right:
Li Be B C O F Ne
(a) To which period do these elements belong?
(b) One element of this period is missing. Which is the missing element and where should it be placed?
(c) Place the three elements: Fluorine, Beryllium and nitrogen in the order of increasing electronegativity.
(d) Which one of the above element belongs to the halogen series?
Solution 11.
(a) Period 2
(b) Nitrogen (N), between carbon and oxygen
(c) Be< N< F
(d) Fluorine
12. Name an
(a) An alkali metal in period 3 and halogen in period 2
(b) The noble gas with 3 shells
(c) The non-metals present in period 2 and metals in period 3.
(d) The element of period 3 with valency 4.
(e) The element in period 3 which does not form an oxide.
(f) The element of lower nuclear charge out of Be and Mg.
(g) Which has higher E.A. Fluorine or Neon?
(h) Which has maximum metallic character Na, Li or K?
Solution 12.
(a) Na and F
(b) Argon
(c) C, N, O and F are non-metals present in period 2 while Na, Mg and Al are metals in period 3.
(d) Silicon
(e) Argon
(f) Mg
(g) Fluorine
(h) K
13.
Solution 13.
(a) The total number of electron shells in an atom determines the period to which the element belongs, and the valence electrons determine the group to which it will belong. So with the help of electronic configuration we can figure out the period and group number of an element.
Elements with one and two valence electrons belong to group 1 and 2 respectively, while to determine the group number of elements with 3 to 8 valence electrons, we add 10 to their valence electrons.
For example an element X has atomic number 15
Its configuration will be:
K shell has 2 electrons, L will have 8, and the remaining 5 will be placed in M shell
Since it has three shells it belongs to period 3 and with 5 valence electrons the element will be placed in five plus ten, that is the 15th group
So with the help of electronic configuration we can figure out the period and group number of an element.
(b) Atomic number = Number of protonsHence, number of protons in K atom = 19
Number of neutrons = Mass number – Atomic number
Hence, number of neutrons in K atom = 39-19 = 20
Number of electrons = Number of protons
Hence, number of electrons= 19
And electronic configuration of K atom = 2, 8, 8, 1
Since K atom has 4 shells, hence it belongs to fourth period.
With one valence electron, it belongs to group 1
Number of protons in P atom = 15
Number of neutrons in P atom = 31-15 = 16
Number of electrons in P atom = 15
And electronic configuration of P atom = 2, 8, 5
Since it has three shells, it belongs to period 3 and with 5 valence electrons Phosphorus is found in five plus ten that is 15th group.
14.
Solution 14.
(a) Fluorine, chlorine and bromine are non-metals with seven valence electrons. They are highly electronegative elements with valency of one. They exist as diatomic molecules. They form ionic compounds with alkali metals.
(b) They are known as halogens. The term means salt forming and therefore compounds containing these elements are called salts.
15.
The last element in each period of the periodic table is a gaseous element with its valence shell completely filled. Except for helium with complete duplet configuration, rest all the 5 gases have complete octet configuration.
These group 18 elements are commonly referred to as noble gases.16.
Solution 16.
The electronic configuration of an element determines its position in Modern Periodic table.
The element with one valence electron is the first while the element with 8 valence electrons is placed in the 18th group of a period.
17.
Solution 17.
(i) The number of valence electrons increases by one as we move from left to right in a period.
The group number 1 and 2 have 1 and 2 valence electrons respectively while group 13 to 18 have group number minus 10 = valence electrons. So,group 13 to 18 have 3, 4, 5, 6, 7 and 8 valence electrons respectively.
(ii) Valency is determined by the number of valence electrons. For elements belonging to group 1, 2 and 13, the valency is equal to the number of valence electrons, so their valency is 1, 2 and 3 respectively.
Since the elements in group 14 to 17 needs to gain electrons to complete their octet configuration. Their valency is 8 minus the number of valence electrons. So their valencies are 4, 3, 2 and 1 respectively.
18.
18.
Solution 18.
(a) Periods
(b) Increases
(c) Decreases
19.
Solution 19.
(a) Since it belongs to group II, it has 2 valence electrons and hence it is a metal.
(b) Barium is placed below calcium in the group. Since, it has more number of shells; it is easier for it to lose its valence electrons to complete its octet configuration. Hence it is more reactive than calcium.
(c) It needs to lose its 2 valence electrons to complete its octet configuration; therefore its valency is also 2.
(d) The formula of its phosphate will be (Ba)3 (PO4)2
(e) As we move from left to right in a period, the size decreases, therefore, it will be smaller than Cesium.
20.
20.
Solution 20.
(a) The number of valence electrons increases by one as we move across any given period.
Therefore as we move from Lithium to Neon in period 2, the valence electrons will increase from 1 to 7.
(b) The metallic character decreases as we move from left to right while the non-metallic character increases.
On going from left to right in a period, the chemical reactivity of elements first decreases and then increases.
For example in period 3, Sodium is the most reactive metal and Chlorine is the most reactive non-metal and Silicon is least reactive.
(c) The oxides of metals are basic and that of non-metals are acidic in general. Therefore since metallic strength decreases and non-metallic strength increases on moving from left to right across a period, the strength of basic oxides decreases, while the strength of acidic oxides increases.
For example, sodium forms a basic oxide, while sulphur and phosphorus form acidic oxides.
21.
(a) Noble gases- H and P
(b) Halogens- G and O
(c) Alkali metals – A and I
(d) D and L have valency of 4
(e) I with atomic number 11.
(f) Cl has the least atomic size in period 3 with atomic number 17.
22.
Solution 22.
As we move down a group, the numbers of shells increases and hence the atomic size increases.
Therefore, Z will have the smallest atomic number followed by Y, while X will have the largest atomic number.
So the elements in order of increasing atomic number will be Z<Y<X.23.
Solution 23.
(a) Since, the distance of the valence electrons from the nucleus keeps on increasing down the group, therefore, the ionization energy keeps on decreasing. Hence the reactivity of alkali metals increases from lithium to francium.
(b) As we move down a group, the size keeps on increasing, so it becomes more difficult for atoms to attract electrons. Thus reactivity of halogens decreases from Fluorine to Astatine.
24.
Solution 24.
(a) Since it belongs to period 3 it has 3 shells, K, L and M. The outermost M shell will have 2 valence electrons as it is placed in group II.
(b) With 2 valence electrons, its valency will be 2.(c) Since it has electronic configuration of 2, 8, 2, its atomic number is 12 and hence X is Magnesium.
(d) It is a metal.
25.
Solution 25.
(a) Group 1since the valence electrons is 1.
(b) With 4 shells T belong to period 4.
(c) Number of electrons = 2+8+8+1=19
(d) T needs to lose one electron to complete its octet hence its valency is 1.
(e) Since it has one valence electron, it is a metal.
26.
Solution 26.
(a) Group 1: Lithium< Sodium< Potassium< Rubidium < Caesium< Francium
Group 17: Fluorine < Chlorine < Bromine< Iodine < Astatine
(b) Group 1: Francium
Group 17: Astatine< Iodine< Bromine< Chlorine< Fluorine
(c) Group 1: Francium< Cesium< Rubidium< Potassium< Sodium< Lithium
Group 17: Astatine< Iodine< Bromine< Chlorine< Fluorine
(d) Group 1: Francium
Group 17: Astatine
(e) Group 1: Lithium>Sodium> Potassium> Rubidium> Cesium> Francium
Group 17: Fluorine > Chlorine> Bromine > Iodine > Astatine
27.
Solution 27.
(a) atomic number
(b) period, non-metallic character
(c) more
(d) number of outer electrons
28.
Solution 28.
(a) Anion is formed by the gain of electrons. Thus the numbers of electrons are more than protons. The effective positive charge in the nucleus is less, so less inward pull is experienced. Hence the size expands. So the size of an atom is greater than the size of parent atom.
(b) Since Argon has stable octet configuration, so due to the inter- electronic repulsions the effect of nuclear pull over the valence shell electrons cannot be seen which results in the bigger size.
(c) Since size of Bromine is bigger than chlorine, so it becomes more difficult for Br atoms to attract electrons. Thus, Cl is more reactive than Br.
29.
Solution 29.29.
(a) Neon
(b) Aluminum
(c) Phosphorus
(d) Calcium
(e) Carbon
30. Name an
(a) An alkali metal in period 3 and halogen in period 2
(b) The noble gas with 3 shells
(c) The non-metals present in period 2 and metals in period 3.
(d) The element of period 3 with valency 4.
(e) The element in period 3 which does not form an oxide.
(f) The element of lower nuclear charge out of Be and Mg.
(g) Which has higher E.A. Fluorine or Neon?
(h) Which has maximum metallic character Na, Li or K?
Solution 30.
(a) Na and F
(b) Argon
(c) C, N, O and F are non-metals present in period 2 while Na, Mg and Al are metals in period 3.
(d) Silicon
(e) Argon
(f) Mg
(g) Fluorine
(h) K
31. Chorine in the periodic table is surrounded by the elements with atomic number 9, 16, 18 and 35.
(a) Which of these have physical and chemical properties resembling chlorine?
(b) Which is more electronegative than chlorine?
Solution 31.
(a) Element with atomic number 9 and 35
(b) Element with atomic number 9.
32.
Solution 32.
(a) Period 1 has 2 elements while period 2 and period 3 have 8 elements each.
(b) Hydrogen and helium
(c) The elements at the end of period 2 and Period 3 have 8 electrons in its outermost shell.
(d) Non metallic, metallic.
33.
Solution 33.
Position in a group: X and Y
Position in a period: Y and X
34.
Solution 34.
Period no. = no. of shells, so n=3
From the formula M2 O3 its valency is 3.
Since it is a metal, its valence shell has 3 electrons.
So its electronic configuration is 2,8,3
Atomic number=13
Hence the metal is Aluminum with valency 3.
35.
Solution 35.
(a) Since the elements in a group have same number of valence electrons, they can either contain metals or non-metals like alkali and alkaline metals have only metals whereas halogens are non-metals.
(b) No two elements have the same number of electrons instead atoms of the same elements in the same group have the same number of valence electrons.
(c) Non-metals have the tendency to gain electrons to attain stable configuration and therefore are said to be electronegative. As we move from left to right the increase in atomic number and decrease in size results in a greater nuclear pull. As a result the non-metallic character increases across a period.
(d) On moving from left to right in a period, the reactivity first decreases and then increases since the tendency to lose electrons first decreases on going from left to right and then from P to Cl, tendency to gain electrons increases, so reactivity increases then. In case of a group, reactivity increases on going down since the tendency to lose electrons increases but for non-metals, reactivity decreases on going down the group as the tendency to gain electrons decreases down the group.
36.Arrange the following in order of increasing radii:
(a) Cl¯, Cl
(b) Mg2+, Mg, Mg+
(c) N, O, P
(a) Cl < Cl¯
(b) Mg2+ < Mg+ < Mg
(c) O < N < P
37. Which element from the following has the highest ionization energy?
(a) P, Na, Cl
(b) F, O, Ne
(c) Ne, He, Ar
Explain your choice.
Solution 37.
(a) Cl
Metals have low ionisation energy and non-metals have high ionisation energy. Also, across the period, ionisation energy tends to increase. The elements P, Na and Cl belong to the third period. Na – Group 1, P – Group 15 and Cl – Group 17.
(b) Ne
Inert gases have zero electron affinity because of their stable electronic configuration.
(c) He
Ionisation energy decreases with an increase in the atomic size, i.e. it decreases as one moves down a group. Ne, He and Ar are inert gases. He – Period 1, Ne – Period 2 and Ar – Period 3.
38.
(a) (iv) Argon
(b) (iii) Calcium
(c) (iii) Helium
1(2003).
Solution 1 (2003).
(a) (Al)2(SO4)3
(b) Covalent bonding
(c) Same number of valence electrons
(d) Helium
(e) 8
(f) Electron affinity
(g) Decreases, atomic number, number of shells
1(2004).(a). The electronegativities(according to Pauling) of the elements in period 3 of the periodic table are as follows with elements arranged in alphabetical order:
Al | Cl | Mg | Na | P | S | Si |
1.5 | 3 | 1.2 | 0.9 | 2.1 | 2.5 | 1.8 |
Arrange the elements in the order in which they occur in the periodic table from left to right.
(The group 1 element first, followed by the group 2 element and so on, up to group 7).
(b)
Solution 1 (2004).
(a) Na, Mg, Al, Si, P, S, Cl
(b)
(i) Lower, higher
(ii) remains the same
(iii) remains the same
1(2005). Parts (a) to (e) refer to change in the properties of elements on moving from left to right across a period of the periodic table. For each property, choose the correct answer.
(a) The non-metallic character of the elements:
(i) Decreases
(ii) Increases
(iii) Remains the same
(iv) Depends on the period
(b) The electronegativity:
(i) Depends on the number of valence electrons
(ii) Remains the same
(iii) Decreases
(iv) Increases
(c) The ionization potential:
(i) goes up and down
(ii) Decreases
(iii) Increases
(iv) Remains the same
(d) The atomic size:
(i) Decreases
(ii) Increases
(iii) Remains the same
(iv) Sometimes increases and sometimes decreases
(e) The electron affinity of elements in group 1 to 7 :
(i) Goes up and then down
(ii) Decreases and then increases
(iii) Increases
(iv) Decreases
Solution 1 (2005).
(a) Increases
(b) Increases
(c) Increases
(d) Decreases
(e) Increases
1(2006). The elements of one short period of the periodic table are given below in order from left to right:
Li Be B C O F Ne
(a) To which period do these elements belong?
(b) One element of this period is missing. Which is the missing element and where should it be placed?
(c) Place the three elements: Fluorine, Beryllium and nitrogen in the order of increasing electronegativity.
(d) Which one of the above element belongs to the halogen series?
Solution 1 (2006).
(a) Period 2
(b) Nitrogen (N), between carbon and oxygen
(c) Be < N < F
(d) Fluorine
Solution 1 (2007).
(a) Thallium has the most metallic character since metallic character increases down the group.
(b) Boron has the highest electronegativity since it has the smallest size in the group.
(c) 3. Since all the elements in a group have same number of valence electrons.
(d) BCl3
(e) The elements in the group to the right of boron group would be less metallic as with the decrease in size and increase in atomic number, it will be more difficult for them to lose electrons.
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